Theoretical Study on Molten Alkali Carbonate Interfaces
نویسندگان
چکیده
منابع مشابه
Molten Carbonate Fuel Cells
Molten carbonate fuel cells use carbonate salts of alkali metals as electrolyte. Due to the highly corrosive nature of the electrolyte, various countermeasures are being developed. MCFCs are expected for high-efficiency power generation systems using hydrocarbon fuels, such as natural gas and coal gas. This article describes the mechanisms of operation and cell degradation, as well as the featu...
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Hybrid plants where a fuel cell and a gas turbine are combined have attracted the attention of the power system community. In this paper, a model is provided of a Molten Carbonate Fuel Cell stack and of the thermo-hydraulic equipment in which it is embedded. The model is worked out from basic physical considerations; however, it is also simple enough for simulation and control purposes. Besides...
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The molten carbonate fuel cell (MCFC) has evolved to current megawatt-scale commercial power plants. When using the fuel cell for electrolysis (MCEC), it provides a promising option for producing fuel gases such as hydrogen, via water electrolysis, and syngas, via co-electrolysis of water and carbon dioxide. The molten carbonate cell can thereby operate reversibly as a dual energy converter for...
متن کاملAnalysis for a Molten Carbonate Fuel Cell
In this paper we analyze a planar model for a molten carbonate electrode of a fuel cell. The model consists of two coupled second-order ordinary diierential equations, one for the concentration of the reactant gas and one for the potential. Restricting ourselves to the case of a positive reaction order in the Butler-Volmer equation, we consider existence, uniqueness, various monotonicity proper...
متن کاملThermal Conductivity of Molten Alkali Halides and Their Mixtures
Thermal conductivity of molten alkali halides and their mixtures with common anions is measured as a function of temperature. Use is made of the most reliable method of coaxial cylinders made of platinum, with radiation heat transfer being taken into account. It is found to vary directly with temperature. Expressions for its temperature dependence are derived from the experimental observations....
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ژورنال
عنوان ژورنال: Langmuir
سال: 2018
ISSN: 0743-7463,1520-5827
DOI: 10.1021/acs.langmuir.8b02907